GRANITOID GEOCHEMICAL
TYPIZATION OF ANGARA-VITIM BATHOLITH
Khrustaljov V.K.
Geological
Institute SB RAS, Ulan-Ude, Russia, smetanina@gin.bscnet.ru
The granitoid geochemical
peculiarities of the Angara-Vitim batholith have been studied during
GTS-200, GS-50 (1960-1986) and research work (1986-2008) (Khrustaljov
1970, 1990, 2000).
Granitoids
of batholith being the main geological background where the whole
picture of the Phanerozoic petrogenesis is observed, are widespread
in West Transbaikalia. By matter composition and structural position,
they are united into the two large groups, i.e. the allochthonous
homogeneous granitoids that have the clearly cutting contacts with
host rocks, and autochthonous ones with distinct features of
formation as a result of sedimentary-metamorphic roof granitization.
The regular-grained and porphyry-like biotite and more rarely
leucocratic granites are mostly spread among the allochthonous
granitoids. The autochthonous granitoids are characterized by mixed
composition. They are represented by porphyry- and gneiss-like
granites, granodiorites, monzonites, granosyenites, plagiogranites
and adamellites.
We
have studied the rocks of 13 autochthonous and 12 allochthonous
massives in the central part and south-east protrusions of batholith.
A
geochemical characteristic of the most typical of them is presented
in Table 1. The analysis of geochemical information on allochthonous
and autochthonous granitoids shows that their most evident
geochemical peculiarity is low, near to clark level of rare element
concentrations. The check of estimates by asymmetry and excess
indicates that distribution of elements in granitoids is mostly
subordinate to normal law of distribution. As a result of rare
element study, the characteristic tendencies of Li, Rb, Zn, Be, Sn, W
and Mo distribution have been revealed. They unite the rocks of
batholith, and at the same time, the significant differences of
autochthonous and allochthonous granitoids are revealed: 1) strong
positive associations of K with Li, Rb, Be, B and negative ones with
Na and F are characteristic of the first ones, while significant
associations lack at all in allochthonous granitoids; 2) high
concentrations of Ba (1-2 clarks) and strong positive associations of
W with Be, and those of Be with B are typical for autochthonous
granitoids; in allochthonous ones, the below clark concentrations of
Ba and strong positive associations of Li with W, Mo, Be and B, those
of Sn with W and Be, of Be and Zn with B, and negative associations
of Rb with Sn, W and Be, of U with Ba and Sr are characteristic.
Conclusions
1.
The
low, near clark level of rare element concentrations is the main
geochemical peculiarity of the studied granitoids.
2.
Close
rock geochemical characteristics of the studied massives obtained for
Li, Rb, Zn, Be, Sn, W and Mo testify to genetic affinity of
granitoids.
3.
Significant
differences in distribution of Ba, Sr, Pb, and Bi in less extent are
confirmed under the conditions of autochthonous and allochthonous
granitoid formation.
4.
Processes
of emanational differentiation in granitoids are suppressed, and
their role in rare element distribution is insignificant.
5.
Areas
of allochthonous and autochthonous granitoid development are barren,
while metasomatically altered autochthonous granitoids in frontal
paleostructures of ensimatic island arcs can be considered as
potentially ore-bearing ones for rare elements and gold.
6.
Average
concentrations of the studied rare elements in granitoids are
recommended to be used as regional clarks for the area of West
Transbaikalia.
References
Khrustaljov V.K. (1990) Geochemistry and ore-bearing of
the Vitim Plateau Paleozoic granitoids. Novosibirsk, Nauka, p.132
Khrustaljov V.K. (2000) Rb-Sr age of Barguzin complex
granitoids. Izd-vo of Buryat Research Centre SB RAS, Ulan-Ude,
p.41-54.
Khrustaljov V.K.,
Lositsky I.V., Kremenetsky I.G. (1970) About some peculiarities of
the Upper River Turka and Kydzhimita Upper Paleozoic granitoids
related to their Sn-bearing (West Transbaikalia). Notes of
Transbaikalian Phil. Geographical Society of the USSR, issue 5,
Chita, P.35-41.
Tauson L.V. (1977)
Geochemical types and potential ore-bearing of granitoids. Nauka,
279p.
Table
1. Intrusive
rock geochemical characteristics of the Ina, Kurba, Kydzhimit, Zaza,
Turka river basins and Vitim right bank.
Complex
|
Massif
|
Rocks
|
Number
of samples
|
Average arithmetical ccntents of elements
|
%
|
ppm
|
ppb
|
K
|
Na
|
Li
|
Rb
|
Pb
|
Zn
|
Sn
|
W
|
Mo
|
Be
|
B
|
F
|
Ba
|
Sr
|
U
|
Au
|
br1/I
|
Olenij
**
|
Granodiorites
|
24
|
3,1
|
2,9
|
34
|
135
|
22
|
78
|
3,1
|
0,7
|
2,1
|
1,8
|
18
|
1300
|
1300
|
1100
|
3,0
|
3,3
|
Ushmanskiy**
|
Monzonites
|
14
|
3,2
|
3,1
|
32
|
110
|
27
|
86
|
3,7
|
0,6
|
2,3
|
2,4
|
18
|
1600
|
2300
|
1000
|
3,8
|
3,7
|
Sholokikan*
|
Porphyry
granites
|
26
|
4,0
|
2,7
|
28
|
190
|
31
|
54
|
2,5
|
0,8
|
1,9
|
2,3
|
25
|
1200
|
2100
|
1050
|
3,6
|
n/a
|
br2/I
|
Devil's
bald peak*
|
Middle-grained.
granites
|
32
|
0,27
|
1,53
|
12
|
n/r
|
5,4
|
80
|
3,3
|
3,7
|
7,7
|
1,3
|
18
|
1000
|
570
|
120
|
4,3
|
2,8
|
Br3/I
|
Akulskiy*
|
Leucogranites
|
28
|
3,6
|
3,4
|
46
|
195
|
31
|
49
|
2,8
|
0,6
|
3,2
|
2,5
|
17
|
680
|
230
|
760
|
4,1
|
2,7
|
Br1/II
|
Zolkhunskiy**
|
Middle-grained
granites
|
16
|
3,4
|
3,0
|
20
|
130
|
22
|
57
|
2,1
|
0,5
|
1,7
|
3,1
|
10
|
340
|
1100
|
270
|
3,3
|
3,2
|
Upper
Kurba**
|
Middle-grained
granites
|
13
|
3,5
|
3,1
|
20
|
120
|
23
|
58
|
2,4
|
0,9
|
0,8
|
2,1
|
13
|
350
|
1100
|
280
|
3,4
|
7,2
|
br1/III
|
Borodinskiy**
|
Granodiorites
|
10
|
2,9
|
2,9
|
18
|
130
|
15
|
52
|
3,8
|
0,7
|
0,6
|
2,4
|
12
|
360
|
1450
|
260
|
3,1
|
4,3
|
br2/IV
|
Solonetz*
|
Porphyry
granites
|
14
|
3,8
|
2,8
|
28
|
180
|
18
|
50
|
3,9
|
0,8
|
1,0
|
2,7
|
9
|
440
|
250
|
350
|
4,5
|
n/à
|
br2/V
|
Upper
Zaza*
|
Porphyry
granites
|
11
|
2,8
|
3,1
|
27
|
91
|
93
|
57
|
2,8
|
0,8
|
0,7
|
1,3
|
11
|
430
|
950
|
400
|
3,9
|
n/à
|
br2/VI
|
Koloushinskiy*
|
Leucogranites
|
9
|
3,4
|
3,8
|
19
|
100
|
27
|
45
|
2,0
|
1,2
|
0,5
|
1,7
|
13
|
370
|
800
|
190
|
4,5
|
n/à
|
Note:
*allochthonous
granitoids; **autochthonous granitoids; basins: Ina – I,
Kurba - II, Kydzhimit - III, Zaza - IV, Turka – V, Vitim
right bank – VI; n/à
– not analyzed element, n/r – not revealed element.
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